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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Hydrogen rearrangements in the mass spectra of some metal complexes of β-diketones

MJ Lacey, CG Macdonald and JS Shannon

Australian Journal of Chemistry 25(12) 2559 - 2565
Published: 1972

Abstract

Hydrogen rearrangements in the mass spectra of copper(11), nickel(11), and oxovanadium(1v) complexes of pentane-2,4-dione, 3-methylpentane-2,4-dione, and 1,3-diphenylpropane-l,3-dione have been studied by deuterium labelling. The results can be interpreted in terms of stepwise reactions which may be preceded by competitive hydrogen-exchange processes.

https://doi.org/10.1071/CH9722559

© CSIRO 1972

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