Ion-molecule reactions in methylene fluoride
AG Harrison and NA McAskill
Australian Journal of Chemistry
24(8) 1611 - 1617
Published: 1971
Abstract
The ion-molecule reactions of CH2F2 in the gas phase were studied using two mass spectrometers, one fitted with a medium-pressure ion source and the other with an ion-trap source. The main reaction was the formation of CH2F+ from CHF2+. The molecular ion and its proton transfer reaction forming CH3F2+ were of lesser importance. The only condensation ion formed was C2H4F3+. Reaction cross sections and rate coefficients for a number of ions at exit energies of 0.2-3.3 eV were measured.https://doi.org/10.1071/CH9711611
© CSIRO 1971