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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Reactivity of transition metal fluorides. VIII. Reactions of rhenium heptafluoride and hexafluoride

JH Canterford, TA O'Donnell and AB Waugh

Australian Journal of Chemistry 24(2) 243 - 247
Published: 1971

Abstract

Oxidation-reduction and halogen-exchange reactions of the higher fluorides of rhenium with a series of selected reagents have been investigated. The results correlate with studies of reactivities of higher fluorides of other transition metals previously reported. The reactions reported provide markedly improved preparative routes to the hexachloride, pentabromide, and pentafluoride of rhenium.

https://doi.org/10.1071/CH9710243

© CSIRO 1971

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