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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Orbital valence force field in tetrahedral oxides and oxyanions of transition metals

M Prasad and AN Pandey

Australian Journal of Chemistry 23(10) 2011 - 2014
Published: 1970

Abstract

The orbital valence force field has been used to calculate the force constants of some oxides and oxyanions of transition metals, e.g. MnO42-, MnO43-, RuO4, RuO4-, Ru042-, and OsO4. The force constants are compared with the Urey-Bradley force constants and have been discussed briefly in relation to relative stabilities of the corresponding ions. The applicability of the Lennard-Jones potential, to approximate the interaction between non-bonded atoms, has been examined.

https://doi.org/10.1071/CH9702011

© CSIRO 1970

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