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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Theory of super-regenerative detection of N.Q.R.

RA Caldwell and S Hacobian

Australian Journal of Chemistry 23(7) 1321 - 1331
Published: 1970

Abstract

Signal intensities of the 35Cl nuclear quadrupole transition in para-dichlorobenzene, obtained using a frequency modulated superregenerative spectrometer, are investigated as a function of quenching frequency. The quenching voltage is applied in the form of pulses of variable on (ton) and off (toff) times. A method is provided for the calculation of (Vs2/Vn2)½ which appears in the detection equation ΔA = aV0In(1 + Vs2/Vn2)½ By applying the theory of nuclear induction to a series of pulses, such as those of a super-regenerative oscillator, it is possible to explain the observed behaviour of signal intensities with operational characteristics and solid state relaxation parameters.

https://doi.org/10.1071/CH9701321

© CSIRO 1970

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