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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Some skeletal-rearrangement processes of phosphoranes upon electron impact

AP Gara, RA Massy-Westropp and JH Bowie

Australian Journal of Chemistry 23(2) 307 - 313
Published: 1970

Abstract

The mass spectra of acyl phosphoranes exhibit peaks which arise by P-O bond formation. The problem of thermal against electron impact rearrangement is considered and the rearrangements have been studied by deuterium labelling. The formation of the fluorenyl cation (m/e 165) has also been investigated.

https://doi.org/10.1071/CH9700307

© CSIRO 1970

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