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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The electronic spectra of acid and basic rhodo salts of chromium(III)

L Dubicki and RL Martin

Australian Journal of Chemistry 23(2) 215 - 222
Published: 1970

Abstract

.The diffuse reflectance spectra of basic rhodo perchlorate, [(NH3)5OCr- (NH3)5](ClO4)4, a t 300°K and 77°K show evidence for both allowed and forbidden hot electronic bands. The near-ultraviolet region containing the well-established four sharp bands in fact contains at least six bands, consisting of two sets of three. The two sets have inverted intensities and originate from different electronic ground states.

The spectrum of acid rhodo chloride, [(NH3)5Cr(OH)Cr(NH3)5]Cl5,H2O, resembles that of a d3 configuration in a near-octahedral field.

https://doi.org/10.1071/CH9700215

© CSIRO 1970

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