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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Carbonyl halides of the Group VI transition metals. XIV. Substitution derivatives of the trihalotetracarbonylmolybdenum(II) anions

JA Bowden and R Colton

Australian Journal of Chemistry 22(5) 905 - 910
Published: 1969

Abstract

The complete series of substituted halocarbonyl anions [Mo(CO)3RPh3X3]- (where R is P, Sb, As; X is Cl, Br) have been characterized as their tetraethyl-ammonium salts. Each substituted anion has been prepared by two distinct methods and all of the compounds can exist as two isomers. Except for the α-isomer of [Mo(CO)3PPh3Br3]- these complexes are reported for the first time.

https://doi.org/10.1071/CH9690905

© CSIRO 1969

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