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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The ligand field spectra of trinuclear chromium(III) and iron(III) basic acetates

L Dubicki and RL Martin

Australian Journal of Chemistry 22(4) 701 - 707
Published: 1969

Abstract

The visible spectra of trinuclear chromium(III) acetates [Cr3O(CH3CO2)6R2]+ can be successfully analysed by means of the ligand field theory for tetragonal fields. The ligands R (R = H2O, NH3, py, DMSO) are relatively labile and may be replaced by several ligands of varying donor strength. The spectra of trinuclear iron(III) acetates [Fe3O(CH3CO2)6R3]+ are poorly resolved but can be interpreted on the basis of a d5 configuration in octahedral fields.

https://doi.org/10.1071/CH9690701

© CSIRO 1969

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