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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The solution dipole moments and the atomic polarizations of chloro-, bromo-, and iodo-benzenes

HH Huang and VR Sullivan

Australian Journal of Chemistry 21(7) 1721 - 1725
Published: 1968

Abstract

Dielectric constant and density measurements of solutions of chloro-, bromo-, and iodo-benzene together with those of p-dichloro-, p-dibromo- and p-diiodo-benzene in carbon tetrachloride at 25º are given. Distortion and atomic polarization values for the polar solutes are estimated by a method proposed by Böttcher; the values are compared with other estimates of PD and PA. To obtain quantitative information of atomic polarizations, using Böttcher's method, greater precision than is usual in solution dielectric constant measurements would be required.

https://doi.org/10.1071/CH9681721

© CSIRO 1968

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