Synthesis of Three Dimensional Cs-γ-CD-MOFs and the Adsorption of Myricetin

Lan Xie; Yangyang Zheng; Jie Deng; Wenkang Jiang; Huijun Liu

doi:10.1071/CH21156

RESEARCH ARTICLE

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Synthesis of Three Dimensional Cs-γ-CD-MOFs and the Adsorption of Myricetin

Lan Xie ^A ^B , Yangyang Zheng ^A , Jie Deng ^A , Wenkang Jiang ^A and Huijun Liu

^A ^B ^C

+ Author Affiliations

- Author Affiliations

^A Department of Chemistry and Chemical Engineering, University of South China, Hengyang, Hunan, 421001, China.

^B Hunan Key Laboratory for the Design and Application of Actinide Complexes, University of South China, Hengyang, Hunan, 421001, China.

^C Corresponding author. Email: liuhuijun@usc.edu.cn

Australian Journal of Chemistry 74(9) 676-683 https://doi.org/10.1071/CH21156
Submitted: 5 July 2021 Accepted: 23 August 2021 Published: 21 September 2021

Abstract

A new Cs-γ-CD-MOF material obtained in colourless large crystals and with a three-dimensional porous structure containing coordinated by cesium ions and γ-cyclodextrin was synthesised by an improved vapour diffusion method. The chemical formula of the Cs-γ-CD-MOF material was C₂₄H₃₄CsO₂₀, with the I₄ space group. Compared with the traditional solvent vapour diffusion method (7 days), this method is advantageous for rapid crystal formation (1 day). Simultaneously, the drug adsortion capacity of γ-CD and Cs-γ-CD-MOFs for myricetin was compared and the results indicated that Cs-γ-CD-MOFs (280.05 mg g⁻¹) have a higher drug adsorption capacity than γ-CD (142.92 mg g⁻¹). Finally, the energy and conformation of the Cs-γ-CD-MOF material for adsorbing the drug myricetin were obtained through molecular docking.

Keywords: MOF, γ-CD, Cs-γ-CD-MOFs, adsorption, myricetin, molecular docking.

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Synthesis of Three Dimensional Cs-γ-CD-MOFs and the Adsorption of Myricetin

Abstract

References

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