Versatile Colorimetric Chemosensor Based on Bis(rhodamine) B Hydrazone for Rapid Detection of Multi-Analytes (Fe3+, Bi3+, Cu2+, and Hg2+) in Aqueous Media

Tamer El Malah; Hany F. Nour

doi:10.1071/CH20046

RESEARCH ARTICLE

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Versatile Colorimetric Chemosensor Based on Bis(rhodamine) B Hydrazone for Rapid Detection of Multi-Analytes (Fe³⁺, Bi³⁺, Cu²⁺, and Hg²⁺) in Aqueous Media

Tamer El Malah

^A ^B and Hany F. Nour

^A ^B

+ Author Affiliations

- Author Affiliations

^A Photochemistry Department, Chemical Industries Research Division, National Research Centre, 33 El Buhouth Street, PO Box 12622, Cairo, Egypt.

^B Corresponding authors. Email: tmara_nrc3000@yahoo.com; hany.nour@daad-alumni.de

Australian Journal of Chemistry 73(11) 1112-1117 https://doi.org/10.1071/CH20046
Submitted: 12 February 2020 Accepted: 31 March 2020 Published: 22 June 2020

Abstract

A new bis(rhodamine) B hydrazone L, bearing two rhodamine chromophores, has been designed and synthesised in 70 % yield. The chemical structure of the new ligand L was characterised using different spectroscopic techniques. The receptor L was utilised for rapid ‘naked eye’ detection of Fe³⁺, Bi³⁺, Cu²⁺, and Hg²⁺ in THF–H₂O (1 : 1, v/v) by displaying significant colour changes. The mechanism of detection of metal ions was based on the ring-opening of the spirolactam rings of L upon recognition. UV/Vis spectrometry was employed to investigate L–metal ion interactions in THF–H₂O (1 : 1, v/v). The stoichiometries of the complexes were determined using Job’s method, which revealed 1 : 2 L–metal ion stoichiometries in the case of L–(Fe³⁺/Bi³⁺/Hg²⁺) complexes, while a 1 : 1 L–metal ion stoichiometry was recognised for the L–Cu²⁺ complex. ¹H NMR spectroscopy was applied to study the L–metal ion interactions in DMSO-d₆ and results are presented.

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Versatile Colorimetric Chemosensor Based on Bis(rhodamine) B Hydrazone for Rapid Detection of Multi-Analytes (Fe3+, Bi3+, Cu2+, and Hg2+) in Aqueous Media

Abstract

References

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Versatile Colorimetric Chemosensor Based on Bis(rhodamine) B Hydrazone for Rapid Detection of Multi-Analytes (Fe³⁺, Bi³⁺, Cu²⁺, and Hg²⁺) in Aqueous Media