Synthesis, Characterisation, and Biological Properties of Oxidovanadium(iv) 3,5-Dinitrosalicylhydroxamate Complexes
Bhanu Priya A , Abhishek Kumar A and Neeraj Sharma A B
+ Author Affiliations
- Author Affiliations
A Department of Chemistry, Himachal Pradesh University, Summer Hill, Shimla-171005, India.
B Corresponding author. Email: neerajsharma_univ@yahoo.co.in
Australian Journal of Chemistry 73(1) 61-72 https://doi.org/10.1071/CH19486
Submitted: 30 September 2019 Accepted: 24 November 2019 Published: 24 January 2020
Abstract
The new oxidovanadium(iv) complexes of composition [VO(3,5(NO2)2C6H2(OH)CONHO)2] 1 and [VO(acac)(3,5(NO2)2C6H2(OH)CONHO)] 2 (where acac = (CH3COCHCOCH3)–] have been synthesised by the reactions of VOSO4·5H2O and [VO(acac)2] with potassium 3,5-dinitrosalicylhydroxamate (3,5-(NO2)2SHK) and characterised by elemental analyses, molar conductivity, magnetic moment measurements and FT-IR, UV-vis, and electron spin resonance (ESR) spectroscopies and mass spectrometry. Infrared spectra of complexes have indicated bonding through oxygen atoms of carbonyl and hydroxamic groups (O,O coordination). The magnetic moment, ESR, and mass spectra of the complexes suggested their monomeric nature, and a distorted square-pyramidal geometry around the vanadium has tentatively been proposed. The electrochemical behaviour of 1 and 2 has been studied by cyclic voltammetry. Thermal behaviour of the complexes studied by thermogravimetric and differential thermal analysis techniques has yielded VO2 as the decomposition product. The in vitro antimicrobial activity of the ligand and complexes has been assayed against pathogenic bacteria and fungi by the minimum inhibitory concentration (MIC) method. The in vitro antioxidant activity of the complexes has been determined by 1,1-diphenyl-2-picrylhydrazyl (DPPH) free radical scavenging method.
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