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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

Assembly, Structure, and Properties of Six Coordination Polymers Based on 1,3,5-Tri-4-pyridyl-1,2-ethenylbenzene

Chen Cao A B , Tian-Yi Gu A , Jian-Guo Zhang A , Ming Dai C , Chun-Yan Ni A E , Zhi-Gang Yao D E and Jian-Ping Lang A B E
+ Author Affiliations
- Author Affiliations

A College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China.

B State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China.

C Suzhou Clean Environment Institute, Jiangsu Sujing Group Co., Ltd, Suzhou 215122, China.

D Analysis and Testing Center, Soochow University, Suzhou 215123, China.

E Corresponding authors. Email: chunyan89.ok@163.com; zhgyao@suda.edu.cn; jplang@suda.edu.cn

Australian Journal of Chemistry 72(10) 751-761 https://doi.org/10.1071/CH19178
Submitted: 20 April 2019  Accepted: 31 May 2019   Published: 21 June 2019

Abstract

Six coordination polymers including [Cd(tpeb)X2]n (1: X = Br, 2: X = I), [Cu(tpeb)I]n (3), [Cd2I2(tpeb)2(1,4-bdc)]n (4), {[Co(tpeb)(dpa)]·MeCN}n (5), and {[Ni2(tpeb)3(oba)2]·solvent}n (6) were prepared from solvothermal reactions of 1,3,5-tri-4-pyridyl-1,2-ethenylbenzene (tpeb) with CdII, CuI, CoII, or NiII salts in the absence or presence of 1,4-benzenedicarboxylic acid (1,4-H2bdc), 2,2′-biphenyldicarboxylic acid (H2dpa), and 4,4′-oxybisbenzoic acid (H2oba). Compounds 13 have 1D chain structures while 4 holds a 2D wave-like network. Compound 5 adopts a 3D (3,5)-connected net with a Schläfli symbol of 33.48.513.63.7 and 6 possesses a 3D 5-connected net with a Schläfli symbol of 42.65.7.82. Compound 2 as a representative photocatalyst shows efficient degradation of rhodamine B in water while 5 displays highly selective sensing of p-nitrophenol in water through fluorescence quenching.


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