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RESEARCH ARTICLE
Contents Vol 71(4)

Facile Synthesis of Pentamethylcyclopentadienyl Ruthenium Half-Sandwich Complexes by Naphthalene Displacement*

Jeremy Stone A , David Jago A , Alexandre Sobolev B , Mark Spackman A and George Koutsantonis A C
+ Author Affiliations
- Author Affiliations

A School of Molecular Sciences, The University of Western Australia, 35 Stirling Highway, Perth, WA 6009, Australia.

B Centre for Microscopy, Characterisation, and Analysis, The University of Western Australia, 35 Stirling Highway, Perth, WA 6009, Australia.

C Corresponding author. Email: george.koutsantonis@uwa.edu.au

Australian Journal of Chemistry 71(4) 289-294 https://doi.org/10.1071/CH18024
Submitted: 17 January 2018  Accepted: 15 March 2018   Published: 27 March 2018

Abstract

Ruthenium half-sandwich complexes are central in a wide range of diverse applications in the field of organometallic chemistry. As such, exploration of their preparation and reactivity is crucial for development of their chemistry. Herein, we present alternative synthetic methods for the preparation of Cp*Ru(dppm)Cl, Cp*Ru(dppe)Cl, Cp*Ru(dppf)Cl, [Cp*Ru(COD)(MeCN)]BF4, and [Cp*Ru(bpy)(MeCN)]BF4 (dppm = 1,2-bis(diphenylphosphino)methane; dppe = 1,2-bis(diphenylphosphino) ethane; dppf = 1,2-bis(diphenylphosphino)ferrocene; COD = 1,5-cyclooctadiene; bpy= 2,2′-bipyridine), starting from the easily accessible [Cp*Ru(η6-C10H8)]BF4. The single-crystal X-ray structure determinations for [Cp*Ru(COD)(MeCN)]BF4, and [Cp*Ru(bpy)(MeCN)]BF4 are also presented.


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