Preparation of CoWO4/g-C3N4 and its Ultra-Deep Desulfurization Property

Pengfei Xing; Rongxiang Zhao; Xiuping Li; Xiaohan Gao

doi:10.1071/CH16320

RESEARCH ARTICLE

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Preparation of CoWO₄/g-C₃N₄ and its Ultra-Deep Desulfurization Property

Pengfei Xing ^A , Rongxiang Zhao ^A ^B , Xiuping Li ^A and Xiaohan Gao ^A

+ Author Affiliations

- Author Affiliations

^A College of Chemistry, Chemical Engineering and Environment Engineering, Liaoning Shihua University, Fushun 113001, China.

^B Corresponding author. Email: zylhzrx@126.com

Australian Journal of Chemistry 70(3) 271-279 https://doi.org/10.1071/CH16320
Submitted: 25 May 2016 Accepted: 6 August 2016 Published: 8 September 2016

Abstract

The ultra-deep desulfurization of fuel oil has become inevitable for environmental protection. Here, CoWO₄/g-C₃N₄ was used as a catalyst, H₂O₂ as an oxidant, and 1-ethyl-3-methylimidazolium ethylsulfate ([EMIM][EtSO₄], IL) as an extractant for the oxidative desulfurization of model oil. Scanning electron microscopy, FT-IR spectroscopy, N₂ adsorption isotherms, and X-ray diffraction were used to confirm the morphology, structure, and properties of the catalysts. The influence of calcination temperature, loading dose of cobalt, amount of H₂O₂, reaction temperature, and other parameters were investigated. The removal rate of sulfide in model oil could reach 92.9 % at 80°C in 180 min under the optimal operation conditions (V(oil) = 5 mL, T = 80°C, m(catalyst) = 0.03 g, V(H₂O₂) = 0.4 mL, t = 180 min, V(IL) = 1.0 mL). In addition, the catalyst was reused five times with no significant reduction in the catalytic activity.

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Preparation of CoWO4/g-C3N4 and its Ultra-Deep Desulfurization Property

Abstract

References

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Preparation of CoWO₄/g-C₃N₄ and its Ultra-Deep Desulfurization Property