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RESEARCH ARTICLE
Contents Vol 69(11)

Aggregation Behaviours of Surface-Active Ionic Liquids 1-Alkyl-3-methylimidazolium Bis(2-ethylhexyl)sulfosuccinate

Jiequn Wu A , Tianxiang Yin A C , Shaoxiong Shi A and Weiguo Shen A B C
+ Author Affiliations
- Author Affiliations

A School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China.

B Department of Chemistry, Lanzhou University, Lanzhou, Gansu 730000, China.

C Corresponding authors. Email: yintx@ecust.edu.cn; shenwg@ecust.edu.cn

Australian Journal of Chemistry 69(11) 1254-1260 https://doi.org/10.1071/CH16122
Submitted: 28 February 2016  Accepted: 24 April 2016   Published: 24 May 2016

Abstract

The systematic investigation of the aggregation behaviours of newly synthesised surface-active ionic liquids 1-alkyl-3-methylimidazolium bis(2-ethylhexyl)sulfosuccinate ([Cnmim][AOT], n = 2, 3, 5, 6, 7) by various techniques is reported. The critical aggregation concentrations (CACs) and the standard Gibbs free energies of aggregation (CH16122_iE1.gif) were determined from measurements on conductivity, fluorescence, and surface tension, which suggested a stronger self-assembly ability in the bulk solution for [Cnmim][AOT] surfactants with longer alkyl chain cations. An interesting structure transition driven by the penetration of the imidazolium cation into the aggregate when n > 4 was found by analysis of the variations of the values of CAC, CH16122_iE2.gif, the degree of counter ion binding (β), and the micropolarity (I1/I3) immediately after the CAC with changing alkyl chain length of the imidazolium cation, which was further confirmed by 1H NMR measurements.


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