Zinc Oxide Nanoparticles-Immobilized Mesoporous Hollow Silica Spheres for Photodegradation of Sodium Dodecylbenzenesulfonate
Parisa Pourdayhimi A , Pei Wen Koh B , Mohamed Mohd Salleh B , Hadi Nur B and Siew Ling Lee B CA Department of Chemistry, Faculty of Science, Universiti Teknologi Malaysia, 81310 Johor Bahru, Johor, Malaysia.
B Center for Sustainable Nanomaterials, Ibnu Sina Institute for Scientific & Industrial Research, Universiti Teknologi Malaysia, 81310 Johor Bahru, Johor, Malaysia.
C Corresponding author: sllee@ibnusina.utm.my
Australian Journal of Chemistry 69(7) 790-797 https://doi.org/10.1071/CH15495
Submitted: 12 August 2015 Accepted: 18 January 2016 Published: 4 March 2016
Abstract
ZnO-Immobilized mesoporous hollow silica spheres (ZnO/xMHSS; x = 15, 30, 50 molar ratio of Zn/Si) were synthesized and examined as photocatalysts toward the degradation of sodium dodecylbenzenesulfonate (SDBS). The hollow structures of MHSS and ZnO-immobilized MHSS composite were evidenced by transmission electron microscopy analysis. X-ray diffraction results confirmed the presence of ZnO and a mesoporous structure in the synthesized materials. N2 adsorption–desorption analysis also depicted the formation of a mesoporous structure and the increased surface area for the ZnO/xMHSS materials. Fourier transform infrared spectroscopy analysis revealed the formation of Si–O–Zn bonds due to interaction between ZnO and MHSS. The photocatalytic testing results indicated that all the ZnO/xMHSS materials showed improved efficiencies of 10–21 % toward the photodegradation of SDBS when compared with bare ZnO. Among the prepared materials, ZnO/15MHSS was the best photocatalyst, which photodegraded 68 % SDBS after 1 h reaction. The kinetic study demonstrated that the photocatalytic reaction followed the second-order model.
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