Synthesis and Characterization of a New Group of Exo-Coordinating O2N2-Donor Macrocycles
Bahram Ghanbari A C , Barzin Safarkoopayeh (Agheli) A , Reze Kia A and Paul R. Raithby B
+ Author Affiliations
- Author Affiliations
A Department of Chemistry, Sharif University of Technology, PO Box 11155-3516, Tehran, Iran.
B Department of Chemistry, University of Bath, Bath, BA2 7AY, UK.
C Corresponding author. Email: ghanbari@sharif.edu
Australian Journal of Chemistry 69(3) 273-278 https://doi.org/10.1071/CH15204
Submitted: 22 April 2015 Accepted: 21 July 2015 Published: 31 August 2015
Abstract
The reaction of 15–18 membered benzodiazacrown ethers with salicylaldehyde afforded n-membered O2N2-donor macrocyclic ligands mounted with 1,3-diazacyclohexane subrings (1–4) in high yields. The products were characterized by FT-IR, 1H, 13C NMR spectroscopy, elemental analyses, and single crystal X-ray studies. The solid state structures revealed strong intramolecular hydrogen bonding between the pendant phenolic group and the tertiary nitrogen of the corresponding macroring.
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