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RESEARCH ARTICLE
Contents Vol 69(1)

Construction of a New ZnII Coordination Polymer for Selective Fluorescence Sensing of CCl4

Jiang-Tao Li A , Yan-Li Dong B and Jing Li A C
+ Author Affiliations
- Author Affiliations

A College of Chemistry and Chemical engineering, The Key Laboratory for Surface Engineering and Remanufacturing in Shaanxi Province, Xi’an University, Xi’an, China.

B College of Sciences, Agricultural University of Hebei, Baoding, China.

C Corresponding author. Email: lijing3157@aliyun.com

Australian Journal of Chemistry 69(1) 56-60 https://doi.org/10.1071/CH15185
Submitted: 14 April 2015  Accepted: 10 June 2015   Published: 28 July 2015

Abstract

Solvothermal reactions of Zn(NO3)2·6H2O, H3tci, and biimpy generated a new ZnII coordination polymer namely [Zn3(tci)2(biimpy)]n·2n(DMF) (1 H3tci = tri(2-carboxyethyl)isocyanurate, biimpy = 2,6-bis(1-imdazoly)pyridine, DMF = N,N-dimethylformamide). Single-Crystal X-ray diffraction analysis reveals that compound 1 features a 2-fold interpenetrated 3D pillar-layered framework based on trinuclear [Zn3(COO)6] cluster subunits. Topological analysis reveals that compound 1 represents a 2-fold interpenetrated (3,8)-connected tfz-d topological network with the point symbol of {43}2{46.618.84}. The luminescence properties of compound 1 dispersed in different organic solvents were systematically investigated. The results indicated that compound 1 can be used as a candidate for selective sensing of CCl4 via a luminescence quenching mechanism.


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