Rheological Properties and Salt Resistance of a Hydrophobically Associating Polyacrylamide
Quanhua Deng A , Haiping Li B , Ying Li A D , Xulong Cao C , Yong Yang C and Xinwang Song C
+ Author Affiliations
- Author Affiliations
A Key Laboratory for Colloid and Interface Chemistry of Education Ministry, Shandong University, Jinan 250100, China.
B State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China.
C Geological Scientific Research Institute, Shengli Oilfield, Dongying 257015, China.
D Corresponding author. Email: yingli@sdu.edu.cn
Australian Journal of Chemistry 67(10) 1396-1402 https://doi.org/10.1071/CH14204
Submitted: 1 April 2014 Accepted: 12 May 2014 Published: 3 July 2014
Abstract
The rheological properties of electrolyte solution of a hydrophobically associating acrylamide-based copolymer (HA-PAM) containing hydrophobically modified monomer and sodium 2-acrylamido-2-methylpropanesulfonic sulfonate were investigated in this paper. The study mainly focussed on effects of electrolyte concentration, temperature, and shear rate on the solution rheological properties. HA-PAM exhibited much stronger salt tolerance and shearing resistance than the commonly used partially hydrolyzed polyacrylamide, and has great potential for application in tertiary oil recovery of oilfields with high salinity. The salt resistance mechanism of HA-PAM in solution was investigated by combining molecular simulation and experimental methods. The structure–performance relationship of the salt-resisting polymer may provide useful guidance for design and synthesis of novel water-soluble polymers with high salt resistance.
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