Magnetic and Electronic Properties of Three New Hetero-Bimetallic Coordination Frameworks [Ru2(O2CR)4][Au(CN)2] (R = Benzoic Acid, Furan-2-carboxylate, or Thiophen-2-carboxylate)
Michael J. Murphy A , Tony D. Keene B , Jason R. Price A , Deanna M. D’Alessandro A C and Cameron J. Kepert A C
+ Author Affiliations
- Author Affiliations
A School of Chemistry, The University of Sydney, NSW 2006, Australia.
B Chemistry, University of Southampton, Highfield, Southampton, SO17 1BJ, UK.
C Corresponding authors. Email: cameron.kepert@sydney.edu.au; deanna.dalessandro@sydney.edu.au
Australian Journal of Chemistry 67(11) 1607-1611 https://doi.org/10.1071/CH14196
Submitted: 1 April 2014 Accepted: 18 July 2014 Published: 23 September 2014
Abstract
The crystal structures and magnetic and electronic properties of three new hetero-bimetallic coordination frameworks, [Ru2(O2CR)4][Au(CN)2] (R = phenyl (1(Ph)), 2-furan (1(Furan)), and 2-thiophene (1(Thio)), have been characterised. Through variation of the functionalised carboxylate group, both the one-dimensional chain structure and properties of the frameworks have been systematically modulated. The magnetic behaviour for each framework has been modelled with a zero-field splitting model and the presence of weak inter-dimer coupling was assessed.
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