Synthesis and Structural Characterisation of Palladium(ii) Complexes with N,N′,N-Tridentate N′-Substituted N,N-Di(2-picolyl)amines and their Application to Methyl Methacrylate Polymerisation

Sunghoon Kim; Dongil Kim; Yujin Song; Ha-Jin Lee; Hyosun Lee

doi:10.1071/CH13731

RESEARCH ARTICLE

Previous Contents Vol 67(6)

Synthesis and Structural Characterisation of Palladium(ii) Complexes with N,N′,N-Tridentate N′-Substituted N,N-Di(2-picolyl)amines and their Application to Methyl Methacrylate Polymerisation

Sunghoon Kim ^A , Dongil Kim ^A , Yujin Song ^A , Ha-Jin Lee ^B ^C and Hyosun Lee ^A ^D

+ Author Affiliations

- Author Affiliations

^A Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, 1370 Sankyuk-dong, Buk-gu, Daegu-city, 702-701, Republic of Korea.

^B Jeonju Center, Korea Basic Science Institute (KBSI), 634-18 Keumam-dong, Dukjin-gu, Jeonju-city, 561-180, Republic of Korea.

^C Department of Chemistry, Chonbuk National University, Dukjin-gu, Jeonju-city, 561-756, Republic of Korea.

^D Corresponding author. Email: hyosunlee@knu.ac.kr

Australian Journal of Chemistry 67(6) 953-961 https://doi.org/10.1071/CH13731
Submitted: 3 January 2014 Accepted: 20 February 2014 Published: 31 March 2014

Abstract

The reaction of [Pd(CH₃CN)₂Cl₂] with N′-substituted N,N-di(2-picolyl)amine-based ancillary ligands, for example N,N-di(2-picolyl)cyclohexylmethylamine (L₁), N,N-di(2-picolyl)benzylamine (L₂), N,N-di(2-picolyl)aniline (L₃), and 1,4-bis[bis(2-pyridylmethyl)aminomethyl]benzene (L₄), in the presence of NaClO₄ in ethanol yields a new series of [(NN′N)PdCl]X (X = ClO₄, Cl) complexes, i.e. mononuclear [L_nPdCl]ClO₄ (L_n = L₁, L₂, L₃) and binuclear [L₄Pd₂Cl₂]Cl₂. X-Ray crystallographic analysis determined that the Pd atom in complexes [(NN′N)PdCl]X showed a slightly distorted square-planar geometry involving three nitrogen atoms and a chlorido ligand. Moreover, the unit cell included a ClO₄^– or Cl^– anion as the counterion. The complex [L₁PdCl]ClO₄ showed the highest catalytic activity for the polymerisation of methyl methacrylate in the presence of modified methylaluminoxane at 60°C among the mononuclear Pd^II complexes. Specifically, the activity of binuclear [L₄Pd₂Cl₂]Cl₂ was 2-fold higher than the corresponding mononuclear [L₂PdCl]ClO₄ per active palladium metal centre.

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Synthesis and Structural Characterisation of Palladium(ii) Complexes with N,N′,N-Tridentate N′-Substituted N,N-Di(2-picolyl)amines and their Application to Methyl Methacrylate Polymerisation

Abstract

References

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