An Enantiomerically Pure Pyridine NC-Palladacycle Derived from [2.2]Paracyclophane
Jean E. Glover A , Paul G. Plieger A and Gareth J. Rowlands A B
+ Author Affiliations
- Author Affiliations
A Institute of Fundamental Sciences, Massey University, Private Bag 11 222, Palmerston North, New Zealand.
B Corresponding author. Email: g.j.rowlands@massey.ac.nz
Australian Journal of Chemistry 67(3) 374-380 https://doi.org/10.1071/CH13440
Submitted: 23 August 2013 Accepted: 21 October 2013 Published: 19 November 2013
Abstract
An enantiomerically pure planar chiral pyridine-based palladacycle was prepared from [2.2]paracyclophane in just four steps. The palladacycle shows potential in catalysis, mediating the Suzuki coupling of an aryl chloride. It also permits the ortho bromination of [2.2]paracyclophane, a reaction that can be hard to achieve selectively.
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