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RESEARCH ARTICLE
Contents Vol 66(11)

Temperature-Driven and Reversible Assembly of Homopolyelectrolytes Derived from Suitably Designed Ionic Liquids in Water

Yuki Kohno A B , Yuki Deguchi A B , Naomi Inoue C and Hiroyuki Ohno A B D
+ Author Affiliations
- Author Affiliations

A Department of Biotechnology, Tokyo University of Agriculture and Technology, 2-24-16, Naka-cho, Koganei, Tokyo 184-8588, Japan.

B Functional Ionic Liquid Laboratories, Graduate School of Engineering, Tokyo University of Agriculture and Technology, 2-24-16, Naka-cho, Koganei, Tokyo 184-8588, Japan.

C Material Analysis Research Laboratories, TEIJIN Ltd, 4-3-2, Asahigaoka, Hino, Tokyo 191-8512, Japan.

D Corresponding author. Email: ohnoh@cc.tuat.ac.jp

Australian Journal of Chemistry 66(11) 1393-1398 https://doi.org/10.1071/CH13301
Submitted: 11 June 2013  Accepted: 15 July 2013   Published: 15 August 2013

Abstract

Polycationic-type homopolymers derived from polymerisable ionic liquids with adequate hydrophobicity were prepared to form spherical nanoparticles in water that changed their diameter as a function of temperature. The diameter change was attributed to a temperature-sensitive and reversible lower critical solution temperature-type phase change of the polymers in water.


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