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RESEARCH ARTICLE
Contents Vol 66(11)

Coordination Assemblies of CoII, NiII, ZnII, and CuII with 3,3′,4,4′-Biphenyltetracarboxylic Acid and Three Positional Isomeric Ligands

Wei Luo A , Di Yao A , Haiye Li A , Fuping Huang A B , Qing Yu A and Hedong Bian A B
+ Author Affiliations
- Author Affiliations

A Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), Department of Chemistry and Chemical Engineering of Guangxi Normal University, Guilin 541004, China.

B Corresponding authors. Email: huangfp2010@163.com; gxnuchem312@yahoo.com.cn

Australian Journal of Chemistry 66(11) 1378-1385 https://doi.org/10.1071/CH13183
Submitted: 17 April 2013  Accepted: 4 July 2013   Published: 15 August 2013

Abstract

Eight different complexes with three positional isomeric dipyridyl ligands (3,3′-Hbpt, 3,4′-Hbpt, and 4,4′-Hbpt) (here, 3,3′-Hbpt = 1H-3,5-bis(3-pyridyl)-1,2,4-triazole, 3,4′-Hbpt = 1H-3-(3-pyridyl)-5-(4-pyridyl)-1,2,4-triazole, and 4,4′-Hbpt = 1H-3,5-bis(4-pyridyl)-1,2,4-triazole), as well as 3,3′,4,4′-biphenyltetracarboxylic acid (H4bptc), namely, {[M(bptc)0.5(3,3′-Hbpt)(H2O)2]·H2O}n (M = Co (1), M = Ni (2)), {[Zn2(bptc)(3,3′-Hbpt)2]·3H2O}n (3), [Co(bptc)0.5(3,4′-Hbpt)(H2O)]n (4), [Ni(bptc)0.5(3,4′-Hbpt)2(H2O)2]n (5), {[Cu(bptc)0.5(3,4′-Hbpt)(H2O)]·H2O}n (6), and {[M(bptc)0.5(4,4′-Hbpt)2(H2O)]·4H2O}n (M = Co (7), and Ni (8)) were synthesised and characterised by single-crystal X-ray diffraction. The crystallographic analysis demonstrates that bptc influences the MII (M = Co, Ni, Cu, and Zn) ions to form 2D layers, which are further connected via the isomeric bpt connectors, leading to many types of coordination polymers, such as 2D layers(for 1–3, 5), 3D four-connected nets with a short Schläfli symbol of (64.82) (for 4, 6), and 3D four-connected nets with a short Schläfli symbol of (64.82)(5.63.72)0.5 (for 7–8). This work demonstrates that the isomeric effects of the bpt ligands influence the construction of these frameworks. The thermal stability of complexes 1–6 was investigated.


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