Preparation of Magnetic Ionic Liquids Composed of Hybrid-Type Anions
Yumiko Takagi A F , Yoriko Kusunoki A , Yukihiro Yoshida B C , Hirofusa Tanaka B , Gunzi Saito B C , Kosuke Katagiri D and Toshiyuki Oshiki E
+ Author Affiliations
- Author Affiliations
A Department of Chemistry, Graduate School of Education, Kagawa University, 1-1 Saiwai-Cho, Takamatsu, Kagawa 760-8522, Japan.
B Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan.
C Faculty of Agriculture, Meijo University, Shiogamaguchi 1-501 Tempaku-ku, Nagoya 468-8502, Japan.
D Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, 1314-1, Shido, Sanuki, Kagawa 769-2193, Japan.
E Department of Applied Chemistry, Graduate School of Natural Science and Engineering, Okayama University, Tsushima-naka, Kita-ku Okayama 700-8530, Japan.
F Corresponding author. Email: ytakagi@ed.kagawa-u.ac.jp
Australian Journal of Chemistry 65(11) 1557-1560 https://doi.org/10.1071/CH12331
Submitted: 24 July 2012 Accepted: 18 September 2012 Published: 1 November 2012
Abstract
1-Ethyl-3-methylimidazolium ethylsulfate ([C2mim][EtSO4]) was mixed with iron(III) chloride·6H2O to give a magnetic ionic liquid composed of the hybrid-type anion, [C2mim][FeCl3·EtSO4], which showed a slightly different magnetic property than [C2mim][FeCl4]. On the other hand, reaction of [C2mim][EtSO4] with cobalt(II) chloride hydrate formed [C2mim]2[CoIICl4], the structure of which was characterised by X-ray crystallographic analysis.
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