Synthesis of Symmetrical, Substituted (alkane-α,ω-diyl)(bis[3,3′-allyl dithioethers]) Monomers for Photoplastic Polymer Networks
Cornelis M. Moorhoff A , Wayne D. Cook A C , Tara Schiller A , Carl Braybrook B and San H. Thang A BA Department of Materials Engineering, Monash University, Clayton, Vic. 3800, Australia.
B Materials Science and Engineering, CSIRO, Clayton, Vic. 3168, Australia.
C Corresponding author. Email: wayne.cook@monash.edu
Australian Journal of Chemistry 65(8) 1165-1176 https://doi.org/10.1071/CH12278
Submitted: 12 June 2012 Accepted: 20 July 2012 Published: 8 August 2012
Abstract
Novel symmetrical (alkane-α,ω-diyl)(bis[3,3′-allyl dithioethers]) compounds and their ether analogues, have been synthesised from (alkane-α,ω-diyl)bis([2-{chloromethyl}allyl]sulfane) precursors, for use in crosslinked polymers which exhibit photoplastic behaviour. Facile synthesis and purification of these monomers was achieved if the alkane-α,ω-diyl moiety had at least one oxygen atom in this linker. The number of sulfur atoms in these monomers was varied from four to two to zero to produce monomers which can be used to evaluate their importance on the photoplasticity behaviour.
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