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RESEARCH FRONT
Contents Vol 65(7)

Synthesis and Structure of a Dimeric, Anionic Thioglycolate Derivative of Manganese Carbonyl1

Yuan Dai A and Brian K. Nicholson A B
+ Author Affiliations
- Author Affiliations

A Chemistry Department, Faculty of Science and Engineering, University of Waikato, Hamilton 3240, New Zealand.

B Corresponding author. Email: b.nicholson@waikato.ac.nz

Australian Journal of Chemistry 65(7) 730-733 https://doi.org/10.1071/CH11395
Submitted: 14 October 2011  Accepted: 8 November 2011   Published: 30 November 2011

Abstract

The thioglycolate anion reacts with BrMn(CO)5 to form a dimeric complex with bridging sulfur atoms of formula [Mn2(thioglycolate)2(CO)6]2–. This was isolated as the Et3NH+ salt and fully characterized for comparison with the previously reported thiosalicylate analogue.


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