Key Factors to Prepare Polyelectrolytes Showing Temperature-Sensitive Lower Critical Solution Temperature-type Phase Transitions in Water
Yuki Kohno A and Hiroyuki Ohno A B
+ Author Affiliations
- Author Affiliations
A Department of Biotechnology, Tokyo University of Agriculture and Technology, 2-24-16, Naka-cho, Koganei, Tokyo 184-8588, Japan.
B Corresponding author. Email: ohnoh@cc.tuat.ac.jp
Australian Journal of Chemistry 65(1) 91-94 https://doi.org/10.1071/CH11378
Submitted: 25 September 2011 Accepted: 3 November 2011 Published: 30 November 2011
Abstract
Tetrabutylphosphonium styrenesulfonate and its homopolymer showed a lower critical solution temperature-type phase transition in water. As the hydrophobicity of these monomeric and polymeric salts affects phase behaviour, the phase transition temperature of the polyelectrolyte was changed by the introduction of monomers having different alkyl chain length on the phosphonium cations.
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