Functionalized Nanoporous Membranes from Reactive Triblock Polymers
Mark A. Amendt A , Monique Roerdink A , Sarah Moench A , William A. Phillip B , Edward L. Cussler B and Marc A. Hillmyer A C
+ Author Affiliations
- Author Affiliations
A Department of Chemistry University of Minnesota, Minneapolis, Minnesota 55455, USA.
B Department of Chemical Engineering and Materials Science University of Minnesota, Minneapolis, Minnesota 55455, USA.
C Corresponding author. Email: hillmyer@umn.edu
Australian Journal of Chemistry 64(8) 1074-1082 https://doi.org/10.1071/CH11130
Submitted: 2 April 2011 Accepted: 21 June 2011 Published: 19 August 2011
Abstract
Hydrophilic and stimuli responsive nanoporous poly(dicyclopentadiene) membranes are prepared using reactive ABC triblock polymers consisting of a chemically etchable ‘A’ block, poly(lactide), various functionalized ‘B’ blocks, and a metathesis-reactive ‘C’ block, poly(styrene-stat-norbornenylethylstyrene).A membrane with a bicontinuous structure is formed by reaction-induced phase separation during the metathesis crosslinking of dicyclopentadiene in the presence of the ABC triblock polymers. Selective etching of the poly(lactide) block exposed the functionality contained in the B block. Hydrophilic membranes are prepared from a triblock polymer with a poly(N,N-dimethylacrylamide) B midblock as evidenced by static contact angle measurements in comparison to AC diblock templated membranes. Temperature responsive membranes are prepared from a triblock polymer with a poly(N-isopropylacrylamide) B block.
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