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RESEARCH FRONT
Contents Vol 64(2)

Photo‐induced Energy Transfer in a Th‐Symmetrical Hexakis‐adduct of C60 Substituted with π‐Conjugated Oligomers

Julien Iehl A , Michel Holler A , Jean‐François Nierengarten A E , K. Yoosaf B , Joanna M. Malicka B , Nicola Armaroli B E , Jean‐Marc Strub C , Alain Van Dorsselaer C E and Béatrice Delavaux‐Nicot D E
+ Author Affiliations
- Author Affiliations

A Laboratoire de Chimie des Matériaux Moléculaires, Université de Strasbourg et CNRS (UMR 7509), Ecole Européenne de Chimie, Polymères et Matériaux (ECPM),25 rue Becquerel, 67087 Strasbourg Cedex 2, France.

B Molecular Photoscience Group, Istituto per la Sintesi Organica e la Fotoreattività (ISOF), Consiglio Nazionale delle Ricerche (CNR), via P. Gobetti 101,40129 Bologna, Italy.

C Laboratoire de Spectrométrie de Masse Bio‐organique, Institut Pluridisciplinaire Hubert Curien (IPHC), Ecole Européenne de Chimie, Polymères et Matériaux (ECPM), Université de Strasbourg et CNRS (UMR 7178), 25 rue Becquerel,67087 Strasbourg Cedex 2, France.

D Laboratoire de Chimie de Coordination (LCC), CNRS, Université de Toulouse (UPS, INP), 205 route de Narbonne, 31077 Toulouse Cedex 4, France.

E Corresponding authors. Email: nierengarten@chimie.u-strasbg.fr, armaroli@isof.cnr.it, vandors@chimie.u-strasbg.fr, Beatrice.Delavaux-Nicot@lcc-toulouse.fr

Australian Journal of Chemistry 64(2) 153-159 https://doi.org/10.1071/CH10319
Submitted: 30 August 2010  Accepted: 15 October 2010   Published: 15 February 2011

Abstract

A stilbene derivative bearing a terminal alkyne unit has been prepared and grafted onto a Th‐symmetrical C60 hexakis‐adduct building block under alkyne/azide copper mediated Huisgen 1,3‐dipolar cycloaddition conditions. The photophysical properties of the resulting fullerene derivative surrounded by 12 conjugated oligomers have been investigated. Upon excitation of the peripheral chromophores, an efficient intramolecular energy transfer to the C60 core has been evidenced.


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