Structurally Perfect Ni3(μ1,3-N3)3 Triangles for a Magnetic Model

Jun-Liang Liu; Xin Bao; Radovan Herchel; Ji-Dong Leng; Zhuo-Jia Lin; Ming-Liang Tong

doi:10.1071/CH10117

RESEARCH ARTICLE

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Structurally Perfect Ni₃(μ_1,3-N₃)₃ Triangles for a Magnetic Model

Jun-Liang Liu ^A , Xin Bao ^A , Radovan Herchel ^B , Ji-Dong Leng ^A , Zhuo-Jia Lin ^A and Ming-Liang Tong ^A ^C

+ Author Affiliations

- Author Affiliations

^A Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education / State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, P. R. China.

^B Department of Inorganic Chemistry, Faculty of Science, Palacký University, tř. 17. listopadu 12, 771 46 Olomouc, Czech Republic.

^C Corresponding author. Email: tongml@mail.sysu.edu.cn

Australian Journal of Chemistry 63(7) 1111-1115 https://doi.org/10.1071/CH10117
Submitted: 14 March 2010 Accepted: 7 June 2010 Published: 15 July 2010

Abstract

Two ideal triangular Ni₃ compounds [Ni₃(μ_1,3-N₃)₃(2,2′-bpy)₃]X₃·3H₂O (X = ClO₄^- (1) and BF₄^- (2); 2,2′-bpy = 2,2′-bipyridine) have, for the first time, been structurally and magnetically characterized, and represent a good model for us to understand the magnetic behaviours in extended azide-bridged nickel(II) complexes with trinuclear subunits.

Acknowledgements

This work was supported by NSFC (Grant nos 20525102, 20821001, 50872157, and J0730420) and the ‘973 Project’ (2007CB815305).

References

Structurally Perfect Ni3(μ1,3-N3)3 Triangles for a Magnetic Model

Abstract

Acknowledgements

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Structurally Perfect Ni₃(μ_1,3-N₃)₃ Triangles for a Magnetic Model