The Discovery of Catalytic Enantioselective Polyvalent Iodine Mediated Reactions
Marsewi Ngatimin A and David W. Lupton A BA School of Chemistry, Monash University, Clayton Campus, Vic. 3800, Australia.
B Corresponding author. Email: david.lupton@sci.monash.edu.au
Australian Journal of Chemistry 63(4) 653-658 https://doi.org/10.1071/CH09625
Submitted: 3 December 2009 Accepted: 3 February 2010 Published: 8 April 2010
Abstract
The use of polyvalent iodine mediated reactions for the synthesis of enantiopure materials has developed into an active field of research. Recently, new chiral aryl iodides, and conditions for their substoichiometric use, have allowed catalytic variants to be achieved. This highlight draws attention to recent discoveries in this emerging field.
Acknowledgement
We acknowledge financial support of the ARC (DP0881137) and Roche (Palo Alto) through donation of equipment and Monash University through an ECR program. We also wish to acknowledge valuable contributions made by the referees regarding an earlier version of this manuscript.
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