Granulated Carbon Nanotubes as the Catalyst Support for Pt for the Hydrogenation of Nitrobenzene
Shao Jin A B , Weizhong Qian A C , Yi Liu A , Fei Wei A , Dezeng Wang A and Jinchang Zhang BA Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing, 100084, China.
B Department of Applied Chemistry, School of Science, Beijing University of Chemical Technology, Beijing, 100029, China.
C Corresponding author. Email: qianwz@tsinghua.edu.cn
Australian Journal of Chemistry 63(1) 131-134 https://doi.org/10.1071/CH09162
Submitted: 17 March 2009 Accepted: 17 August 2009 Published: 8 January 2010
Abstract
Granulated Pt/carbon nanotubes (CNTs) were found to have a much better catalytic activity in the liquid phase hydrogenation of nitrobenzene than Pt/activated carbon (AC). The granulated CNTs had much larger pores than the AC particles, which gave a faster mass transfer rate of H2 that helped produce aniline with high selectivity.
Acknowledgements
This work is supported by FANEDD (200548), NSFC (20606020, 20736007), NBRPC (2006CB932702).
[1]
J. M. Planeix,
N. Coustel,
B. Coq,
V. Brotons,
V. Kamlar,
R. Dutatre,
P. Geneste,
P. Bernier,
P. M. Ajayan,
J. Am. Chem. Soc. 1994, 116, 7935.
| Crossref | GoogleScholarGoogle Scholar |
CAS |
| Crossref | GoogleScholarGoogle Scholar |
CAS |
| Crossref | GoogleScholarGoogle Scholar |
CAS |
| Crossref | GoogleScholarGoogle Scholar |
CAS |
| Crossref | GoogleScholarGoogle Scholar |
CAS |
| Crossref | GoogleScholarGoogle Scholar |
CAS |
| Crossref | GoogleScholarGoogle Scholar |
CAS |
| Crossref | GoogleScholarGoogle Scholar |
CAS |
| Crossref | GoogleScholarGoogle Scholar |
CAS |
| Crossref | GoogleScholarGoogle Scholar |
CAS |
| Crossref | GoogleScholarGoogle Scholar |
CAS |
| Crossref | GoogleScholarGoogle Scholar |
CAS |
| Crossref | GoogleScholarGoogle Scholar |
CAS |
| Crossref | GoogleScholarGoogle Scholar |
CAS |
| Crossref | GoogleScholarGoogle Scholar |
CAS |
| Crossref | GoogleScholarGoogle Scholar |
CAS |
| Crossref | GoogleScholarGoogle Scholar |
CAS |
| Crossref | GoogleScholarGoogle Scholar |
CAS |
|
CAS |
| Crossref | GoogleScholarGoogle Scholar |
CAS |