Synthesis of Naturally Occurring Arsenic-Containing Carbohydrates

Pedro Traar; Alice Rumpler; Tobias Madl; Gerald Saischek; Kevin A. Francesconi

doi:10.1071/CH08461

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Synthesis of Naturally Occurring Arsenic-Containing Carbohydrates

Pedro Traar ^A , Alice Rumpler ^A , Tobias Madl ^B , Gerald Saischek ^A and Kevin A. Francesconi ^A ^C

+ Author Affiliations

- Author Affiliations

^A Institute of Chemistry, Karl-Franzens University Graz, Universitaetsplatz 1, 8010 Graz, Austria.

^B Institute of Structural Biology, Helmholtz Zentrum Muenchen; and Biomolecular NMR-Spectroscopy, Department Chemie, Technische Universitaet Muenchen, Lichtenbergstrasse 4, 85747 Garching, Germany.

^C Corresponding author. Email: kevin.francesconi@uni-graz.at

Australian Journal of Chemistry 62(6) 538-545 https://doi.org/10.1071/CH08461
Submitted: 24 October 2008 Accepted: 7 January 2009 Published: 10 June 2009

Abstract

We report the synthesis of (S)-2′-hydroxy-3′-sulfonylpropyl 5-deoxy-5-dimethylarsinoyl-β-d-riboside ammonium salt and (S)-2′-hydroxy-3′-sulfooxypropyl 5-deoxy-5-dimethylarsinoyl-β-d-riboside ammonium salt, two common naturally occurring arsenicals.

Acknowledgements

The Austrian Science Fund (FWF P16816) and the Austrian Academy of Sciences (DOC Scholarship) are thanked for financial support. Robert V. Stick, Rudolf Pietschnig, and Wolfram Wielandt are gratefully thanked for helpful and supportive discussions.

References

Synthesis of Naturally Occurring Arsenic-Containing Carbohydrates

Abstract

Acknowledgements

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