Synthesis and Properties of Novel Chiral Ionic Liquids from l-Proline
Hong-Shuai Gao A , Zhi-Guo Hu A , Jian-Ji Wang A C , Zhao-Fa Qiu A and Feng-Qiu Fan BA Department of Chemistry, Henan Key Laboratory of Environmental Pollution Control, Henan Normal University, Xinxiang, Henan 453007, China.
B Department of Chemical and Biomolecular Engineering, Johns Hopkins University, Baltimore, MD 21218, USA.
C Corresponding author. Email: jwang@henannu.edu.cn
Australian Journal of Chemistry 61(7) 521-525 https://doi.org/10.1071/CH07298
Submitted: 22 August 2007 Accepted: 15 May 2008 Published: 16 July 2008
Abstract
A novel class of chiral ionic liquids with chiral cations directly derived from natural l-proline has been synthesized and their physical properties such as melting point, thermal degradation, and specific rotation have been characterized. Further, their potential use in chiral recognition was demonstrated by studying interactions with racemic Mosher’s acid salt.
Acknowledgements
The present work was supported by the National Natural Science Foundation of China (Project Numbers 20273019 and 20573034).
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