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REVIEW
Contents Vol 60(10)

Recent Advances in Microwave-Assisted Polymer Synthesis

Sebastian Sinnwell A B and Helmut Ritter A C
+ Author Affiliations
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A Institute for Organic Chemistry and Macromolecular Chemistry, Chair for Preparative Polymer Chemistry, Heinrich-Heine-University of Duesseldorf, 40225 Duesseldorf, Germany.

B Present address: Centre for Advanced Macromolecular Design (CAMD), School of Chemical Sciences and Engineering, The University of New South Wales, Sydney, NSW 2052, Australia.

C Corresponding author. Email: h.ritter@uni-duesseldorf.de




Dr. Sebastian Sinnwell was born in 1977 in Hamburg, Germany. He studied chemistry at the University of Duesseldorf (Germany) and received his Diploma in 2004. In his Ph.D. thesis he investigated the influence of microwave irradiation on the ring-opening polymerization of lactones and cyclic imino ethers under supervision of Professor H. Ritter (Duesseldorf, Germany). After he obtained his Ph.D. in 2007 he has started a post-doctoral project in the group of Professor C. Barner-Kowollik (Sydney, Australia). Current investigations are focused on the living/controlled radical polymerization via RAFT process.


Professor Dr. Helmut Ritter was born in November 1948. After studying chemistry at the University of Marburg (1967–1972) and completing his doctorate with Professor H. Ringsdorf in Mainz, he was employed as head of a laboratory at Bayer AG. He started his university career in 1982 as a professor for organic chemistry at the University of Wuppertal, where he got his habilitation in 1989. Professor Ritter left the University of Wuppertal in 1997 and moved to the University of Mainz where he took over as chair of Polymer Chemistry. In October 2001, he was appointed at the Heinrich-Heine-University Düsseldorf, and since then he is the head of the department for Organic Chemistry and Macromolecular Chemistry.

Australian Journal of Chemistry 60(10) 729-743 https://doi.org/10.1071/CH07219
Submitted: 26 June 2007  Accepted: 24 August 2007   Published: 9 October 2007

Abstract

In the past few years the use of microwave irradiation in polymer science has become a well-established technique to drive and promote chemical reactions. The main advantages of microwave heating are a strong reduction in reaction time and a high potential to contribute to green and sustainable chemistry. This article provides a short review of recent examples in the field of microwave-assisted polymer synthesis with special emphasis on radical polymerizations, step-growth polymerizations, ring-opening polymerizations, and polymer modifications.


References


[1]   Loupy A., Microwaves in Organic Synthesis, 2nd edn, 2006 (Wiley VCH: Weinheim).

[2]   Kappe C. O., Stadler A., Microwaves in Organic and Medicinal Chemistry, 1st edn 2005(Wiley VCH: Weinheim).

[3]   C. O. Kappe, D. Dallinger, Nat. Rev. Drug Discovery 2006, 5,  51.
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