New Heterocycle-Based Organic Molecule with Two-Photon Induced Blue Fluorescent Emission
Pin Shao A , Zhen Li A , Jingui Qin A C , Hongmei Gong B , Sha Ding B and Ququan Wang B CA Department of Chemistry, Wuhan University, Wuhan 430072, China.
B Department of Physics, Wuhan University, Wuhan 430072, China.
C Corresponding authors. Email: jgqin@whu.edu.cn; qqwang@whu.edu.cn
Australian Journal of Chemistry 59(1) 49-52 https://doi.org/10.1071/CH05179
Submitted: 27 July 2005 Accepted: 12 December 2005 Published: 31 January 2006
Abstract
A new heterocycle-based quadrupolar molecule containing 2,5-diphenyl-1,3,4-oxadiazole as the π-centre and two carbazoles as end units has been synthesized. It exhibits two-photon induced blue emission, and its two-photon absorption cross section in the femtosecond region is measured to be 239 × 10−50 cm4 s photon−1 at a wavelength of 788 nm.
Acknowledgments
This work was supported by the National Natural Science Foundation of China (grants no. 90201002 and 10474075).
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