A New Two-Armed Colorimetric Chemosensor for Fluoride
Jin-Long Wu A , Yong-Bing He A B , Lan-Hua Wei A , Ling-Zhi Meng A , Ting-Xian Yang A and Xin Liu AA Department of Chemistry, Wuhan University, Wuhan, Hubei 430072, China.
B Corresponding author. Email: ybhe@whu.edu.cn
Australian Journal of Chemistry 58(1) 53-57 https://doi.org/10.1071/CH04228
Submitted: 20 September 2004 Accepted: 10 November 2004 Published: 14 January 2005
Abstract
The neutral anion receptor 1 was synthesized by an easy method with high yield. The binding properties of anions with 1 were examined by UV-vis and 1H NMR spectroscopy. Receptor 1 can form a 1 : 2 complex with F−, and 1 : 1 complexes with AcO− and H2PO4− anions, respectively, by multiple hydrogen-bonding interactions. There is an observable colour change for the complex formed by 1 and F−.
Acknowledgment
We thank the National Natural Science Foundation for financial support (grant no. 20372054).
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