Structural and Magnetic Properties of the Coordination Polymer Mn(dca)2 (H2 O)2 ·2Me4 pyz, dca = Dicyanamide (N(CN)2 - ), Me4 pyz = Tetramethylpyrazine
A. M. Kutasi, A. R. Harris,
S. R. Batten, B. Moubaraki and K. S. Murray
Australian Journal of Chemistry
55(5) 311 - 313
Published: 02 August 2002
Abstract
The structure of Mn(dca)2(H2O)2·2Me4pyz (dca = dicyanamide, N(CN)2-; Me4pyz = tetramethylpyrazine) contains one-dimensional polymeric chains of Mn(dca)2(H2O)2. The Me4pyz molecules hydrogen-bond to the water ligands, and form ···Me4pyz···H2O···Me4pyz···H2O··· chains which flank either side of the coordination polymer chains. Magnetic susceptibility studies show that very weak intra-chain antiferromagnetic-coupling occurs.https://doi.org/10.1071/CH02065
© CSIRO 2002
