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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

A New Catalyst for the Reductive Elimination of Acylated Glycosyl Bromides to Form Glycals

R. V. Stick, K. A. Stubbs, D. M. G. Tilbrook and A. G. Watts

Australian Journal of Chemistry 55(2) 83 - 85
Published: 05 June 2002

Abstract

Ethylene-N,N-bis(salicylideneiminato)oxovanadium(IV) {VO(salen)} has been developed as a useful catalyst for the reductive elimination of acylated glycosyl bromides to form glycals, both in the pyranose and furanose series, using zinc/ammonium chloride/methanol or zinc/acetic acid/acetonitrile.

https://doi.org/10.1071/CH02011

© CSIRO 2002

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