A New Catalyst for the Reductive Elimination of Acylated Glycosyl Bromides to Form Glycals
R. V. Stick, K. A. Stubbs, D. M. G. Tilbrook and A. G. Watts
Australian Journal of Chemistry
55(2) 83 - 85
Published: 05 June 2002
Abstract
Ethylene-N,N-bis(salicylideneiminato)oxovanadium(IV) {VO(salen)} has been developed as a useful catalyst for the reductive elimination of acylated glycosyl bromides to form glycals, both in the pyranose and furanose series, using zinc/ammonium chloride/methanol or zinc/acetic acid/acetonitrile.https://doi.org/10.1071/CH02011
© CSIRO 2002