Controlled Synthesis of Novel Dibenzene-1,2-diol Mannich Bases
Marcus J. Caulfield, Tiziana Russo and David H. Solomon
Australian Journal of Chemistry
53(7) 545 - 549
Published: 2000
Abstract
The synthesis of a number of novel dibenzene-1,2-diol Mannich bases can be achieved in good yields by the condensation of 2-methoxyphenol, formaldehyde and secondary diamines. The newly developed synthetic method uti lizes 2-methoxyphenol instead of benzene-1,2-diol providing a useful tool for greater control over reaction products.Keywords: Aminoalkylation; catechol; Mannich base; synthesis.
https://doi.org/10.1071/CH00079
© CSIRO 2000