Preparation and X-Ray Structure of cis -3-Pentamethyldisilanylcyclohexyl p -Nitrobenzoate
Alison J. Green and Jonathan M. White
Australian Journal of Chemistry
50(1) 27 - 30
Published: 1997
Abstract
The title compound was prepared in three steps from cyclohex-2-enone. The C(alkyl){O(ester) bond distance is 1·471(3) Å which is not significantly different to that for other cyclohexyl p-nitrobenzoates. This suggests that the γ-pentamethyldisilanyl substituent has very little effect on the ester substituent in the ground state.https://doi.org/10.1071/C96128
© CSIRO 1997