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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The Chlorination of 2-Tert-Butyl-4,6-Dimethylphenol and 2,6-Di-Tert-Butyl-4-Methylphenol. The Formation of 5,6-Dichloro-4-Methylenecyclohex-2-Enones

MP Hartshorn, MC Judd and WT Robinson

Australian Journal of Chemistry 39(12) 2121 - 2143
Published: 1986

Abstract

The chlorination in acetic acid of 2-t-butyl-4,6-dimethylphenol (1) gives two chloromethylene compounds (4) and (5), and trichloro ketones (6) and (7). In contrast, 2,6-di-t-butyl-4-methylphenol (2) gives six chlorination products (14)-(19). The notable feature of the reactions is the modification of the 4-methyl groups of the phenols (1) and (2). The modes of formation of all reaction products are described. X-ray structure determinations are reported for compounds (5),(6),(15),(17), (19) and (21).

https://doi.org/10.1071/CH9862121

© CSIRO 1986

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