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Australian Journal of Chemistry Australian Journal of Chemistry Society
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RESEARCH ARTICLE

Metal template reactions. I. Benzilic acid rearrangement of 2,2'-pyridil and related compounds promoted by nickel(II) and cobalt (II) ions

DSC Black and RC Srivastava

Australian Journal of Chemistry 22(7) 1439 - 1447
Published: 1969

Abstract

Reaction of 2,2?-pyridil with methanolic nickel(II) and cobalt(II) acetates results in the formation of metal complexes of 2,2?-pyridilic acid. This benzilic acid rearrangement is undergone similarly by 2,2?- quinaldil but not by benzil, 2,2?-furil, or I-phenyl-2-(2?- pyridyl)ethane-1,2-dione. Possible mechanisms for this rearrangement are discussed.

https://doi.org/10.1071/CH9691439

© CSIRO 1969

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