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RESEARCH ARTICLE
Contents Vol 68(3)

A Metal-Free and Ionic Liquid-Catalyzed Aerobic Oxidative Bromination in Water

Jian Wang A , Shu-Bin Chen A , Shu-Guang Wang A and Jing-Hua Li A B
+ Author Affiliations
- Author Affiliations

A College of Pharmaceutical Science, Zhejiang University of Technology, No. 18 Chaowang Road, Hangzhou, China.

B Corresponding author. Email: lijh@zjut.edu.cn

Australian Journal of Chemistry 68(3) 513-517 https://doi.org/10.1071/CH14161
Submitted: 26 March 2014  Accepted: 12 July 2014   Published: 6 October 2014

Abstract

A metal-free aerobic oxidative bromination of aromatic compounds in water has been developed. Hydrobromic acid is used as a bromine source and 2-methylpyridinium nitrate ionic liquid is used as a recyclable catalyst. Water is used as the reaction mediate. This is the first report of aerobic oxidative bromination using only catalytic amount of metal-free catalyst. This system shows not only high bromine atom economy, but also high bromination selectivity. The possible mechanism and the role of the catalyst in this system have also been discussed.


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