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RESEARCH ARTICLE
Contents Vol 70(5)

Supramolecular Assemblies of Cucurbit[10]uril Based on Outer Surface Interactions

Yu-Qing Yao A , Qing Liu A , Ying Huang A , Qian-Jiang Zhu A , Yun-Qian Zhang A , Xin Xiao A , Zhu Tao A C and Gang Wei B C
+ Author Affiliations
- Author Affiliations

A Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China.

B CSIRO Manufacturing PO Box 218, Lindfield, NSW 2070, Australia.

C Corresponding authors. Email: gzutao@263.net; gang.wei@csiro.au

Australian Journal of Chemistry 70(5) 637-641 https://doi.org/10.1071/CH16552
Submitted: 30 September 2016  Accepted: 23 November 2016   Published: 16 December 2016

Abstract

Using an established method, we isolated a large quantity of cucurbit[10]uril (Q[10]) and prepared Q[10]-based supramolecular assemblies via different approaches. For example, the structure-directing agent [CdCl4]2– was used or the Q[10] molecule itself acted as a self-structure-directing agent to form different Q[10]-based supramolecular assemblies through the outer surface interaction of Q[10]. Generally, the Q[10]-based supramolecular assemblies possess porous features that suggest that Q[n]-based compounds could be used to manufacture molecular sieves and sensors and applied in absorption and separation technologies.


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